It was reported that the lack of a tooltip made its purpose unclear.
This can be solved by just copying PlacesViewRow’s eject_button tooltip.
https://bugzilla.gnome.org/show_bug.cgi?id=766909
<property name="valign">center</property>
<property name="margin-start">4px</property>
<property name="icon-name">media-eject-symbolic</property>
+ <property name="tooltip-text" translatable="yes">Unmount</property>
<style>
<class name="sidebar-button"/>
</style>